acapelierds.py

Created by klfraimbow

Created on April 13, 2023

1.14 KB

Titrante titre


Titrage : chercher concentration
quantite molaire d une espece

Titrant : solution connait V et C
Titree : connait V mais pas C
 
na/a = nb/b 
b*na=a*nb
b*Ca*Va=a*Cb*Vb
Ca= a/b* Cb*Vb/Va
  = Cb*Vb/Va

1er cas: titre acide fort H30+
HA+H20 -> A- + H30+
OH- sera la solution titrante
Eq sup: 
  H30+ + OH- -> 2H20
Kr= 10**14
  = H20/H30+*OH- = 1/10**-14 (Ke)

2eme cas: titre ac faible AH
HA+H20 = A- +H20
OH- sera la solution titrante 
Eq sup:
  AH + OH- = A- + H2O
Kr = A-/HA*OH-
   = 10**14 * Ka

3eme cas: titre base forte OH-
B- + H20 => OH- + BH
hydroxyde
H30+ sera la solution titrante
Eq sup:
  OH- + H30+ => 2H20
Kr=important

4eme cas: base faible B-
B- + H20 = HB + OH-
H30+ sera la solution titrante
Eq sup:
B- + H30+ = HB + H20
Kr= BH/ B-*H30+ = 1/Ka = 10**14

dpH/dVtitrant
V1E volume a equivalance 

2 tangeantes parralleles courbe saut pH
segement perpendiculaire au 2
M mileur segment puis droite parallele
equidistant

n titree = n titrant
na = nb
Ca * Va = Cb * Vb
Ca = Cb*Vb/Va

Ve/2 demi eq
A- = AH

5Fe + 1 Mn0

n(Fe)/5  =  n(Mno)/1

courbe decroissante = basique 
         croissante = acide
inflexion 

si le ph pas egal 7 faible

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