c101acidebase.py

Created by alten01

Created on February 02, 2023

792 Bytes


CONSTANTE D ACIDITE
Ka=[A-]eq*[H3O+]eq/[AH]eq
associee a la reaction de lacide
AH avec leau:
AH(aq)+H2O(l)<=>A-(aq)+H3O+(aq)
Cette constante implique que:
pKa=-log(Ka)
Ka=10**-pKa

FORCE DUN ACIDE DUNE BASE DS LEAU
Un acide est dautant plus fort quand 
son pKa est petit(pH proche de 0)
Une base est dautant plus forte 
quand son pKa est grand(pH proche
de 14)

PH DUNE SOLUTION CONTENANT LE
COUPLE AH/A- :
pH=pKa+log( ([A-]eq)/([AH]eq) )
Si [AH]eq=[A-]eq alors pH=pKa

PRODUIT IONIQUE DE LEAU :
Ke=[H3O+]eq*[HO-]eq
associee a la reaction d autoprolyse 
de leau : 2H2O<=>H3O+ + HO-

pKe = -log * Ke   =>Ke=10**-pKe
le pKe est compris entre 14-25C

A 25C: Ke=1.0*10**-14 et pKe=14

0           pKe/2         pKe
----------------------------->
[H3O+]>[HO-] H3O=HO    H3O<HO

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